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HP_Problem.out
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HP_Problem.out
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*******************************************************************************
NASA-GLENN CHEMICAL EQUILIBRIUM PROGRAM CEA2, MAY 21, 2004
BY BONNIE MCBRIDE AND SANFORD GORDON
REFS: NASA RP-1311, PART I, 1994 AND NASA RP-1311, PART II, 1996
*******************************************************************************
problem hp
p(psi) = 500.00000
phi = 1.00000
react
fuel=CH4 wt=100.00000 t,k=298.00000
ox=O2 wt=100.00000 t,k=298.00000
output trans
plot p t h mw cp gammas phi rho son
end
OPTIONS: TP=F HP=T SP=F TV=F UV=F SV=F DETN=F SHOCK=F REFL=F INCD=F
RKT=F FROZ=F EQL=F IONS=F SIUNIT=T DEBUGF=F SHKDBG=F DETDBG=F TRNSPT=T
TRACE= 0.00E+00 S/R= 0.000000E+00 H/R= 0.000000E+00 U/R= 0.000000E+00
P,BAR = 34.473652
REACTANT WT.FRAC (ENERGY/R),K TEMP,K DENSITY
EXPLODED FORMULA
F: CH4 1.000000 -0.897291E+04 298.00 0.0000
C 1.00000 H 4.00000
O: O2 1.000000 -0.530002E+00 298.00 0.0000
O 2.00000
SPECIES BEING CONSIDERED IN THIS SYSTEM
(CONDENSED PHASE MAY HAVE NAME LISTED SEVERAL TIMES)
LAST thermo.inp UPDATE: 9/09/04
g 7/97 *C tpis79 *CH g 4/02 CH2
g 4/02 CH3 g11/00 CH2OH g 7/00 CH3O
g 8/99 CH4 g 7/00 CH3OH srd 01 CH3OOH
tpis79 *CO g 9/99 *CO2 tpis91 COOH
tpis91 *C2 g 6/01 C2H g 1/91 C2H2,acetylene
g 5/01 C2H2,vinylidene g 4/02 CH2CO,ketene g 3/02 O(CH)2O
srd 01 HO(CO)2OH g 7/01 C2H3,vinyl g 6/96 CH3CO,acetyl
g 1/00 C2H4 g 8/88 C2H4O,ethylen-o g 8/88 CH3CHO,ethanal
g 6/00 CH3COOH srd 01 OHCH2COOH g 7/00 C2H5
g 7/00 C2H6 g 8/88 C2H5OH g 7/00 CH3OCH3
srd 01 CH3O2CH3 g 8/00 C2O tpis79 *C3
n 4/98 C3H3,1-propynl n 4/98 C3H3,2-propynl g 2/00 C3H4,allene
g 1/00 C3H4,propyne g 5/90 C3H4,cyclo- g 3/01 C3H5,allyl
g 2/00 C3H6,propylene g 1/00 C3H6,cyclo- g 6/01 C3H6O,propylox
g 6/97 C3H6O,acetone g 1/02 C3H6O,propanal g 7/01 C3H7,n-propyl
g 9/85 C3H7,i-propyl g 2/00 C3H8 g 2/00 C3H8O,1propanol
g 2/00 C3H8O,2propanol g 7/88 C3O2 g tpis *C4
g 7/01 C4H2,butadiyne g 8/00 C4H4,1,3-cyclo- n10/92 C4H6,butadiene
n10/93 C4H6,1butyne n10/93 C4H6,2butyne g 8/00 C4H6,cyclo-
n 4/88 C4H8,1-butene n 4/88 C4H8,cis2-buten n 4/88 C4H8,tr2-butene
n 4/88 C4H8,isobutene g 8/00 C4H8,cyclo- g10/00 (CH3COOH)2
n10/84 C4H9,n-butyl n10/84 C4H9,i-butyl g 1/93 C4H9,s-butyl
g 1/93 C4H9,t-butyl g12/00 C4H10,n-butane g 8/00 C4H10,isobutane
g 8/00 *C5 g 5/90 C5H6,1,3cyclo- g 1/93 C5H8,cyclo-
n 4/87 C5H10,1-pentene g 2/01 C5H10,cyclo- n10/84 C5H11,pentyl
g 1/93 C5H11,t-pentyl n10/85 C5H12,n-pentane n10/85 C5H12,i-pentane
n10/85 CH3C(CH3)2CH3 g 2/93 C6H2 g11/00 C6H5,phenyl
g 8/00 C6H5O,phenoxy g 8/00 C6H6 g 8/00 C6H5OH,phenol
g 1/93 C6H10,cyclo- n 4/87 C6H12,1-hexene g 6/90 C6H12,cyclo-
n10/83 C6H13,n-hexyl g 6/01 C6H14,n-hexane g 7/01 C7H7,benzyl
g 1/93 C7H8 g12/00 C7H8O,cresol-mx n 4/87 C7H14,1-heptene
n10/83 C7H15,n-heptyl n10/85 C7H16,n-heptane n10/85 C7H16,2-methylh
n 4/89 C8H8,styrene n10/86 C8H10,ethylbenz n 4/87 C8H16,1-octene
n10/83 C8H17,n-octyl n 4/85 C8H18,n-octane n 4/85 C8H18,isooctane
n10/83 C9H19,n-nonyl g 3/01 C10H8,naphthale n10/83 C10H21,n-decyl
g 8/00 C12H9,o-bipheny g 8/00 C12H10,biphenyl g 6/97 *H
g 1/01 HCO g 6/01 HCCO g 4/02 HO2
tpis78 *H2 g 5/01 HCHO,formaldehy g 6/01 HCOOH
g 8/89 H2O g 6/99 H2O2 g 6/01 (HCOOH)2
g 5/97 *O g 4/02 *OH tpis89 *O2
g 8/01 O3 n 4/83 C(gr) n 4/83 C(gr)
n 4/83 C(gr) g11/99 H2O(cr) g 8/01 H2O(L)
g 8/01 H2O(L)
SPECIES WITH TRANSPORT PROPERTIES
PURE SPECIES
BINARY INTERACTIONS
O/F = 3.989263
EFFECTIVE FUEL EFFECTIVE OXIDANT MIXTURE
ENTHALPY h(2)/R h(1)/R h0/R
(KG-MOL)(K)/KG -0.55932260E+03 -0.16563198E-01 -0.11211849E+03
KG-FORM.WT./KG bi(2) bi(1) b0i
*C 0.62334580E-01 0.00000000E+00 0.12493744E-01
*H 0.24933832E+00 0.00000000E+00 0.49974975E-01
*O 0.00000000E+00 0.62502344E-01 0.49974975E-01
POINT ITN T C H O
1 23 3525.243 -16.913 -10.376 -15.019
THERMODYNAMIC EQUILIBRIUM COMBUSTION PROPERTIES AT ASSIGNED
PRESSURES
CASE =
REACTANT WT FRACTION ENERGY TEMP
(SEE NOTE) KJ/KG-MOL K
FUEL CH4 1.0000000 -74605.353 298.000
OXIDANT O2 1.0000000 -4.407 298.000
O/F= 3.98926 %FUEL= 20.043038 R,EQ.RATIO= 1.000000 PHI,EQ.RATIO= 1.000000
THERMODYNAMIC PROPERTIES
P, BAR 34.474
T, K 3525.24
RHO, KG/CU M 2.6457 0
H, KJ/KG -932.21
U, KJ/KG -2235.23
G, KJ/KG -43393.0
S, KJ/(KG)(K) 12.0448
M, (1/n) 22.494
(dLV/dLP)t -1.05159
(dLV/dLT)p 1.9247
Cp, KJ/(KG)(K) 8.3907
GAMMAs 1.1256
SON VEL,M/SEC 1211.1
TRANSPORT PROPERTIES (GASES ONLY)
CONDUCTIVITY IN UNITS OF MILLIWATTS/(CM)(K)
VISC,MILLIPOISE 1.1556
WITH EQUILIBRIUM REACTIONS
Cp, KJ/(KG)(K) 8.3907
CONDUCTIVITY 23.4882
PRANDTL NUMBER 0.4128
WITH FROZEN REACTIONS
Cp, KJ/(KG)(K) 2.2070
CONDUCTIVITY 4.4209
PRANDTL NUMBER 0.5769
MOLE FRACTIONS
*CO 0.14543
*CO2 0.13559
COOH 0.00001
*H 0.02548
HCO 0.00001
HO2 0.00022
*H2 0.05710
H2O 0.44275
H2O2 0.00002
*O 0.02380
*OH 0.09869
*O2 0.07089
* THERMODYNAMIC PROPERTIES FITTED TO 20000.K
PRODUCTS WHICH WERE CONSIDERED BUT WHOSE MOLE FRACTIONS
WERE LESS THAN 5.000000E-06 FOR ALL ASSIGNED CONDITIONS
*C *CH CH2 CH3 CH2OH
CH3O CH4 CH3OH CH3OOH *C2
C2H C2H2,acetylene C2H2,vinylidene CH2CO,ketene O(CH)2O
HO(CO)2OH C2H3,vinyl CH3CO,acetyl C2H4 C2H4O,ethylen-o
CH3CHO,ethanal CH3COOH OHCH2COOH C2H5 C2H6
C2H5OH CH3OCH3 CH3O2CH3 C2O *C3
C3H3,1-propynl C3H3,2-propynl C3H4,allene C3H4,propyne C3H4,cyclo-
C3H5,allyl C3H6,propylene C3H6,cyclo- C3H6O,propylox C3H6O,acetone
C3H6O,propanal C3H7,n-propyl C3H7,i-propyl C3H8 C3H8O,1propanol
C3H8O,2propanol C3O2 *C4 C4H2,butadiyne C4H4,1,3-cyclo-
C4H6,butadiene C4H6,1butyne C4H6,2butyne C4H6,cyclo- C4H8,1-butene
C4H8,cis2-buten C4H8,tr2-butene C4H8,isobutene C4H8,cyclo- (CH3COOH)2
C4H9,n-butyl C4H9,i-butyl C4H9,s-butyl C4H9,t-butyl C4H10,n-butane
C4H10,isobutane *C5 C5H6,1,3cyclo- C5H8,cyclo- C5H10,1-pentene
C5H10,cyclo- C5H11,pentyl C5H11,t-pentyl C5H12,n-pentane C5H12,i-pentane
CH3C(CH3)2CH3 C6H2 C6H5,phenyl C6H5O,phenoxy C6H6
C6H5OH,phenol C6H10,cyclo- C6H12,1-hexene C6H12,cyclo- C6H13,n-hexyl
C6H14,n-hexane C7H7,benzyl C7H8 C7H8O,cresol-mx C7H14,1-heptene
C7H15,n-heptyl C7H16,n-heptane C7H16,2-methylh C8H8,styrene C8H10,ethylbenz
C8H16,1-octene C8H17,n-octyl C8H18,n-octane C8H18,isooctane C9H19,n-nonyl
C10H8,naphthale C10H21,n-decyl C12H9,o-bipheny C12H10,biphenyl HCCO
HCHO,formaldehy HCOOH (HCOOH)2 O3 C(gr)
H2O(cr) H2O(L)
NOTE. WEIGHT FRACTION OF FUEL IN TOTAL FUELS AND OF OXIDANT IN TOTAL OXIDANTS