You can customize the schedule view label by using TimeFormat property in each ScheduleView in Xamarin.Forms SfSchedule.
You can also refer the following article.
DayView
Customize the DayView label by setting TimeFormat property in DayLabelSettings.
<schedule:SfSchedule.DayViewSettings>
<schedule:DayViewSettings>
<schedule:DayViewSettings.DayLabelSettings>
<schedule:DayLabelSettings TimeFormat="hh:mm"/>
</schedule:DayViewSettings.DayLabelSettings>
</schedule:DayViewSettings>
</schedule:SfSchedule.DayViewSettings>
WeekView
Customize the WeekView label by setting TimeFormat property in WeekLabelSettings.
<schedule:SfSchedule.WeekViewSettings>
<schedule:WeekViewSettings>
<schedule:WeekViewSettings.WeekLabelSettings>
<schedule:WeekLabelSettings TimeFormat="hh:mm"/>
</schedule:WeekViewSettings.WeekLabelSettings>
</schedule:WeekViewSettings>
</schedule:SfSchedule.WeekViewSettings>
WorkWeekView
Customize the WorkWeekView label by setting TimeFormat property in WorkWeekLabelSettings.
<schedule:SfSchedule.WorkWeekViewSettings>
<schedule:WorkWeekViewSettings>
<schedule:WorkWeekViewSettings.WorkWeekLabelSettings>
<schedule:WorkWeekLabelSettings TimeFormat="hh:mm"/>
</schedule:WorkWeekViewSettings.WorkWeekLabelSettings>
</schedule:WorkWeekViewSettings>
</schedule:SfSchedule.WorkWeekViewSettings>
TimelineView
Customize the TimelineView label by setting TimeFormat property in of LabelSettings.
<schedule:SfSchedule.TimelineViewSettings>
<schedule:TimelineViewSettings>
<schedule:TimelineViewSettings.LabelSettings>
<schedule:TimelineLabelSettings TimeFormat="hh:mm"/>
</schedule:TimelineViewSettings.LabelSettings>
</schedule:TimelineViewSettings>
</schedule:SfSchedule.TimelineViewSettings>