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Full Dimensional PES of intramolecular H-transfer in Catecholate

overview

PES_Catecholate calculates the potential energy in full dimensional (33)
normal mode space. The normal modes are dimensionless.  The output is in
wavenumber (cm^-1)

Dependencies: C++17 compatibility.

How to give grid input

For any given grid, input file is to be generated in ./input_data folder.
Each line of input file for grid has to have 33 elements corresponding to 33
dimensionless normal mode displacements.

In this sample, the file used is ./input_data/catecholate_TS_IRC_grid.dat
that contains the points along the IRC path

For each grid, the code needs to be recompiled with the following changes:

1) In /include/PES_catecholate/constants.hpp ==>

    Set
       inline constexpr int N_pts = Ngrid
    where Ngrid is the no. of grid points for which potential to be
    calculated, i.e. number of lines in the grid input file.

2) In /src/constants.cpp ==>

    a) Set 
         extern const std::string gridfile = "filename"
       where filename.dat in the ./input_data folder corresponding to grid
       locations. Note: extension .dat is automatically added.

    b) Based on desired output type, following changes are to be made ==>

       If the output energy is desired in binary format, 
       i)  set the following =>
             extern const std::string outputtype = "bin"
       ii) also set 
             extern const std::string pot_savefile = "filename"
           where filename.bin will be the output file. Note: extension .bin
           is automatically added.

           After running the executable, output will be saved in the
           ./output_data folder.

       If ascii output is desired:
       i)  set the following
             extern const std::string outputtype = "dat"
           The potential values will be printed on screen and can be
           redirected to an output file
       ii) also comment out the following line 
             extern const std::string pot_savefile

How to run

make clean
make
make move
cd bin
./PES

Currently, the code will run for IRC path (80 points) and produce a binary output file of energies.

For any queries

Please contact deba.bhat.90@gmail.com or debabratab@iisc.ac.in

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